1.0 Introduction
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1.1 Background of Study
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The study of factors influencing the accelerated corrosion of cargo oil tanks has evolved over several decades, reflecting growing understanding and technological advancements. Early research on tank corrosion focused primarily on the effects of chemical exposure and environmental conditions. in the 1970s and 1980s, studies highlighted the significant role of sulfur compounds in crude oil, which were found to contribute to the accelerated deterioration of tank materials (Moggridge & Hedges, 2002). The 2000s brought advancements in corrosion prevention technologies and materials. Researchers developed more corrosion-resistant coatings and materials designed to withstand the aggressive conditions inside cargo oil tanks. The focus shifted towards understanding the combined effects of chemical, and operational factors on corrosion rates. Recent studies have integrated these factors into comprehensive models for predicting and mitigating corrosion in cargo oil tanks (Liu et al., 2011).
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The corrosion of cargo oil tanks presents a significant challenge for the maritime industry due to its impact on vessel safety and operational costs. Cargo oil tanks are crucial for the storage of various types of oil, including crude oil and refined products, which are inherently corrosive due to their chemical composition. The presence of sulfur, water, and other reactive compounds in these oils can contribute to the accelerated corrosion of tank materials (Moggridge & Hedges, 2002).
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Historically, the problem of tank corrosion has been compounded by inadequate maintenance practices and environmental conditions that favor corrosion. The maritime environment, characterized by high humidity, fluctuating temperatures, and saltwater exposure, creates an ideal setting for corrosion to occur. For instance, the formation of corrosive electrolytes on tank surfaces due to high humidity and salt deposits accelerates corrosion (Liu et al., 2011).
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Cargo oils refer to petroleum products transported in bulk, such as crude oil or refined products. These oils can contain corrosive compounds like sulfur, which accelerate corrosion in storage tanks (Moggridge & Hedges, 2002). The accelerated corrosion of cargo oil tanks is a critical issue that significantly affects the longevity and safety of maritime vessels. Corrosion in these tanks is primarily driven by several interacting factors, including the chemical composition of the cargo, environmental conditions, and operational practices. The aggressive nature of cargo oils, especially those containing sulfur and other corrosive elements, can lead to rapid deterioration of tank materials (Moggridge & Hedges, 2002).
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The presence of water and microbial activity within the tanks can exacerbate corrosion processes, particularly in the presence of oxygen, leading to severe material degradation (Smith et al., 2009). Environmental conditions such as temperature and humidity also play a significant role in corrosion rates. Elevated temperatures can accelerate chemical reactions that contribute to corrosion, while high humidity levels can promote the formation of corrosive electrolytes on tank surfaces (Liu et al., 2011). Therefore, in Nigeria where the research was carried out, the activities that was conducted is to know the factors influencing accelerated corrosion of cargo oil tanks.
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1.2 Statement of Problems
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Investigation revealed that the accelerated corrosion of cargo oil tanks presents several critical issues that compromise the safety and economic efficiency of maritime operations. One significant problem is the chemical aggressiveness of cargo oils, particularly those with high sulfur content, which accelerates the degradation of tank materials (Moggridge & Hedges, 2002). Environmental conditions also contribute to the problem, with high humidity and temperature fluctuations creating an environment conducive to corrosion. Elevated humidity promotes the formation of corrosive electrolytes, while temperature variations can lead to thermal stresses that exacerbate material degradation (Liu et al., 2011).
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Furthermore, the presence of water and microbial activity within tanks introduces additional corrosive elements and accelerates corrosion rates (Smith et al., 2009). It is against the backdrop that this study seeks to address these problems by assessing the factors influencing accelerated corrosion of cargo oil tanks.
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1.3 Aim and Objectives of Study
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The aim of the study is to investigate the factors influencing accelerated corrosion of cargo oil tanks. In achieving this aim, the following specific objectives were laid out as follows:
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\r\n- To examine the influence of environmental conditions, such as humidity and temperature fluctuations, on the corrosion process.
\r\n- To assess the impact of operational practices, including cleaning and maintenance procedures, on the severity of corrosion.
\r\n- To analyze the chemical composition of cargo oils and their effect on corrosion rates in cargo oil tanks.
\r\n- To evaluate the role of microbial activity in accelerating corrosion within cargo oil tanks.
\r\n- To propose practical recommendations and strategies for reducing corrosion and extending the service life of cargo oil tanks.
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1.4 Research Questions
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The study came up with research questions so as to be able to ascertain the above stated objectives. The specific research questions for the study are stated below as follows:
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\r\n- How does the chemical composition of cargo oils affect the rate and severity of corrosion in cargo oil tanks?
\r\n- What is the impact of environmental conditions, such as temperature fluctuations and humidity levels, on the corrosion of cargo oil tanks?
\r\n- How do operational practices, including cleaning and maintenance, contribute to the corrosion of cargo oil tanks?
\r\n- To what extent does microbial activity influence the corrosion process within cargo oil tanks?
\r\n- What are the most effective strategies for mitigating corrosion and enhancing the durability of cargo oil tanks?
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1.5 Research Hypothesis
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In order to pursue the objective of this study, the following generalized statements have been designed to guide and aids in obtaining the result for the experiment to be conducted. For this work, the null hypothesis will be represented with H0 while the alternative hypothesis will be represented with hypothesis H1.
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\r\n- H01: The accelerated corrosion of cargo oil tanks is significantly influenced by the chemical composition of the cargo oils, with higher sulfur content leading to increased corrosion rates.
\r\n- H02: Microbial activity within cargo oil tanks accelerates the corrosion process by producing corrosive byproducts.
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1.6 Significance of Study
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This study will provide valuable insights into the specific factors that contribute to the accelerated corrosion of cargo oil tanks, thereby enhancing understanding of the underlying mechanisms. The findings will inform the development of more effective maintenance and cleaning practices, which will help in mitigating corrosion and reducing maintenance costs. Additionally, the study will contribute to the creation of improved materials and coatings that will better withstand corrosive environments.
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1.7 Scope of Study
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The scope of the research is focused on the factors influencing accelerated corrosion of cargo oil tanks using Meditarian Shipping Company in Lagos State as a case study.
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1.8 Limitations of the Study
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The research study was limited by several factors that affected its scope and depth.
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\r\n- Insufficient data from cargo oil tanks, due to restricted access or incomplete records, was a significant limitation, impacting the comprehensiveness of the analysis.
\r\n- Frequent power failures during data collection periods disrupted the research process, leading to delays in obtaining and processing critical information.
\r\n- Financial and time constraints also restricted the ability to conduct extensive testing and analysis, potentially affecting the thoroughness and generalizability of the findings.
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1.9 Definition of Terms
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Corrosion:
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The deterioration of materials, typically metals, due to chemical reactions with their environment. In cargo oil tanks, corrosion often results from exposure to corrosive substances in cargo oils and environmental conditions (Jones, 1996).
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Environmental Conditions:
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It refers to the factors such as temperature, humidity, and atmospheric exposure that influence the rate of corrosion. Elevated humidity and temperature fluctuations contribute to accelerated corrosion by promoting corrosive reactions and the formation of electrolytes (Liu et al., 2011).
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Cargo Oils:
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They are petroleum products transported in bulk, such as crude oil or refined products. These oils can contain corrosive compounds like sulfur, which accelerate corrosion in storage tanks (Moggridge & Hedges, 2002).
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Microbial Activity:
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The presence and activity of microorganisms within cargo oil tanks that can contribute to corrosion. Microbes can produce corrosive byproducts and promote the formation of biofilms that exacerbate material degradation (Smith et al., 2009).
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Maintenance Practices:
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Procedures and activities involved in the upkeep and cleaning of cargo oil tanks. Inadequate maintenance practices can lead to the accumulation of corrosive residues and accelerate corrosion (Jones, 1996).
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Corrosion-Resistant Coatings:
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Protective layers applied to the surfaces of cargo oil tanks to prevent or reduce corrosion. These coatings are designed to withstand aggressive environments and extend the service life of the tanks (Liu et al., 2011).
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Electrolytes:
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Solutions that conduct electricity and can accelerate corrosion by facilitating corrosive reactions on metal surfaces. Electrolytes can form from water, salts, and other substances within cargo oil tanks (Jones, 1996).
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Chemical Composition:
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It is the specific chemical makeup of cargo oils, including sulfur and other reactive elements, which influences the corrosion process. Oils with higher sulfur content are more corrosive and contribute to faster deterioration of tank materials (Moggridge & Hedges, 2002).
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Corrosive Residues:
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Accumulated substances within cargo oil tanks that contribute to corrosion. These residues can include remnants of cargo oils and byproducts of chemical reactions (Smith et al., 2009).
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Biofilms:
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Collections of microorganisms that adhere to surfaces within cargo oil tanks. Biofilms can create localized environments that promote corrosion and contribute to material degradation (Smith et al., 2009).
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